Yes. You can control each limit for both cards separately in the app. For example, you can keep a usage limit of US$4,000 on your physical card and US$6,000 on the virtual card.
Just go to "Cards"> "Card you want to set the limit for"> "Daily Purchase Limit."
Remember that both card limits are shared; the sum of the two card limits of US$ 10,000/day, US$ 30,000/month, and US$ 100,00/year.